sure.
	Filter on any lead that has a blank value in that field and then run Sync Lead to SFDC.
	That should do it. 
	I'd test this on a lead you know has a value in SFDC to make sure Marketo doesn't overwrite it with a blank.
	 
Usually Marketo will sense that the field has changed in SFDC and sync it over automatically, but in this case that may not happen.