Can you see your email if you remove the pdf link? If not, it's not an issue with the pdf link.
Did you or your admin setup Marketo with CNAME? If so, is that working alright? Can you see landing pages using "View Approved Page" button and "Preview Page"?
If you're using Marketo from company's internal network, try using from non-company internal network. I'm having a similar problem when previewing my emails from my company internal network because our company's internal DNS does not contain information on the CNAME I've setup on Marketo.