There are several reasons this could happen I can think of off the top of my head. Delivered means it was accepted by the intended recipients mail server. It could still have gone to their junk folder, have them check there. It could also be quarantined within the server, which would be an issue on their end and not with Marketo. Have them whitelist your ip's and sending domain on their end and it shouldn't be an issue. Bottom line, delivered status can be a pretty broad and ambiguous status. Really it just means the email you sent was not rejected.