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You could make sure there is an Email Invalid flag synced to Marketo's email invalid flag. SFDC does have a hidden option for this when it says "Confirm Email Address" if SFDC received a bounce.
Another method is to setup an automatic campaign:
Trigger: Data Value Changes: Email Invalid IS TRUE
Flow: SFDC Email Invalid Flag IS TRUE
Send Alert (if you want)
Thanks Josh. That helps a lot!