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They will have to wait till the next cast (Tuesday in your case) to get the first nurture email.
If it was a welcome email or something that you wanted to go out right away, you could make a smart campaign to do this when they get added to the nurture, like in the flow say add to stream -- and send email --.
This does mean though that there's a chance of two emails in a row if they went through that smart campaign on Tuesday at 6am and then the cast goes out at 10am (unless you have communicaiton limits set).